Three-dimensionally shaped article production member, three-dimensionally shaped article production apparatus, three-dimensionally shaped article production method, and three-dimensionally shaped article

ABSTRACT

A three-dimensionally shaped article production member is a member used in a three-dimensionally shaped article production apparatus for producing a three-dimensionally shaped article by stacking a layer formed using a composition containing particles. The member is placed on a stage and comes in contact with the layer, and has a portion provided with pores in a contact surface with the layer.

BACKGROUND

1. Technical Field

The present invention relates to a three-dimensionally shaped articleproduction member, a three-dimensionally shaped article productionapparatus, a three-dimensionally shaped article production method, and athree-dimensionally shaped article.

2. Related Art

There has been known a technique for shaping a three-dimensionallyshaped article by forming material layers (unit layers) using acomposition containing a powder (particles) and stacking the layers(see, for example JP-A-2003-53847). In this technique, athree-dimensionally shaped article is shaped by repeating a procedure asfollows. First, a material layer is formed by thinly spreading a powderto a uniform thickness, and a bonded part is formed by selectivelybonding the powder particles to one another only in a desired portion ofthis material layer. As a result, a member in the form of a thin plate(hereinafter referred to as “cross-sectional member”) is formed in thebonded part in which the powder particles are bonded to one another.Thereafter, a material layer is further formed thinly on the materiallayer, and a bonded part is formed by selectively bonding the powderparticles to one another only in a desired portion. As a result, a newcross-sectional member is formed also in the newly formed materiallayer. At this time, the newly formed cross-sectional member is bondedalso to the previously formed cross-sectional member. By repeating sucha procedure to stack a cross-sectional member (bonded part) in the formof a thin plate one by one, a three-dimensionally shaped article can beshaped.

However, in the related art, in a production process for athree-dimensionally shaped article, a powder (particles) constituting acomposition is blown (scattered) so that the dimensional accuracy of athree-dimensionally shaped article to be produced is sometimesdeteriorated.

SUMMARY

An advantage of some aspects of the invention is to provide athree-dimensionally shaped article production member capable ofproducing a three-dimensionally shaped article with excellentdimensional accuracy with excellent productivity and excellentstability, to provide a three-dimensionally shaped article productionapparatus capable of producing a three-dimensionally shaped article withexcellent dimensional accuracy with excellent productivity and excellentstability, to provide a three-dimensionally shaped article productionmethod capable of producing a three-dimensionally shaped article withexcellent dimensional accuracy with excellent productivity and excellentstability, and to provide a three-dimensionally shaped article withexcellent dimensional accuracy produced using the three-dimensionallyshaped article production method and the three-dimensionally shapedarticle production apparatus.

The advantage can be achieved by the invention described below.

A three-dimensionally shaped article production member according to anaspect of the invention is a member used in a three-dimensionally shapedarticle production apparatus for producing a three-dimensionally shapedarticle by stacking a layer formed using a composition containingparticles, wherein the member is placed on a stage and comes in contactwith the layer, and has a portion provided with pores in a contactsurface with the layer.

According to this, a three-dimensionally shaped article productionmember capable of producing a three-dimensionally shaped article withexcellent dimensional accuracy with excellent productivity and excellentstability can be provided.

It is preferred that the three-dimensionally shaped article productionmember according to the aspect of the invention is in the form of aplate.

According to this, the three-dimensionally shaped article productionmember can be stably placed on the stage, and the handleability of thethree-dimensionally shaped article production member becomesparticularly excellent.

It is preferred that the three-dimensionally shaped article productionmember according to the aspect of the invention includes a first portionwhich has the pores and a second portion which does not have the poresor has the pores which are sealed.

According to this, the three-dimensionally shaped article productionmember can be favorably adsorbed onto the stage by suction, and thestability of the production of a three-dimensionally shaped article canbe made particularly excellent.

It is preferred that in the three-dimensionally shaped articleproduction member according to the aspect of the invention, the secondportion is provided in a region which does not overlap with a portionconstituting a tangible part of the three-dimensionally shaped articlein the layer when the layer is viewed in plan view.

According to this, the dimensional accuracy of the finally obtainedthree-dimensionally shaped article can be made higher.

It is preferred that the three-dimensionally shaped article productionmember according to the aspect of the invention has a portionconstituted by a sintered body of particles constituted by a metalmaterial or a ceramic material.

According to this, the strength, heat resistance, durability, and thelike of the three-dimensionally shaped article production member can bemade particularly excellent. Further, the shape stability andhandleability thereof also become excellent, and thus, it is alsopossible to favorably transfer the member in a state where a stackedbody obtained by staking a plurality of layers is placed thereon.

It is preferred that in the three-dimensionally shaped articleproduction member according to the aspect of the invention, the averagepore diameter of the pores is 0.1 μm or more and 100 μm or less.

According to this, the suction of the layer through the pores can bemore favorably performed. Further, the ease of cleaning or washing,durability, and the like of the three-dimensionally shaped articleproduction member can be made particularly excellent. In addition, thethree-dimensionally shaped article production member can be easily andreliably produced by a sintering method or the like.

It is preferred that in the three-dimensionally shaped articleproduction member according to the aspect of the invention, thecomposition contains a solvent in addition to the particles.

According to this, the solvent can be efficiently removed from thelayer. In the related art, in the case where a composition containingparticles and a solvent is used as a layer forming composition, it isdifficult to sufficiently remove the solvent from the inside of thelayer of the composition, and therefore, problems arise such that themechanical strength or dimensional accuracy of a three-dimensionallyshaped article cannot be made sufficiently excellent, and when thecontent of the solvent in the layer is tried to be sufficientlydecreased, the productivity of a three-dimensionally shaped article issignificantly decreased, the durability and reliability of athree-dimensionally shaped article are decreased, etc. However,according to the invention, even in the case where a compositioncontaining a solvent is used as the layer forming composition, theoccurrence of problems as described above can be reliably prevented.Accordingly, the effect of the invention is more remarkably exhibited inthe case where the layer forming composition contains particles and asolvent.

A three-dimensionally shaped article production apparatus according toan aspect of the invention includes the three-dimensionally shapedarticle production member according to the aspect of the invention.

According to this, a three-dimensionally shaped article productionapparatus capable of producing a three-dimensionally shaped article withexcellent dimensional accuracy with excellent productivity and excellentstability can be provided.

A three-dimensionally shaped article production apparatus according toan aspect of the invention is an apparatus for producing athree-dimensionally shaped article by stacking a layer formed using acomposition containing particles, and includes a three-dimensionallyshaped article production member having pores, a stage, on which thethree-dimensionally shaped article production member is placed, and asuction unit for sucking the layer through the pores.

According to this, a three-dimensionally shaped article productionapparatus capable of producing a three-dimensionally shaped article withexcellent dimensional accuracy with excellent productivity and excellentstability can be provided.

A three-dimensionally shaped article production method according to anaspect of the invention is a method for producing a three-dimensionallyshaped article by stacking a layer and includes a layer forming step offorming the layer using a layer forming composition containing particlesin a region which overlaps with a three-dimensionally shaped articleproduction member having pores when viewed in plan view, and a bondedpart forming step of forming a bonded part by bonding the particles toone another, wherein a series of these steps is performed repeatedly,and when performing a series of these steps, the layer is sucked throughthe pores.

According to this, a three-dimensionally shaped article productionmethod capable of producing a three-dimensionally shaped article withexcellent dimensional accuracy with excellent productivity and excellentstability can be provided.

It is preferred that in the three-dimensionally shaped articleproduction method according to the aspect of the invention, the bondedpart is formed by applying a binding solution to the layer formed usingthe layer forming composition.

According to this, the mechanical strength of a three-dimensionallyshaped article can be made excellent. Further, the energy amountrequired for forming the bonded part can be decreased.

A three-dimensionally shaped article according to an aspect of theinvention is produced using the three-dimensionally shaped articleproduction apparatus according to the aspect of the invention.

According to this, a three-dimensionally shaped article with excellentdimensional accuracy can be provided.

A three-dimensionally shaped article according to an aspect of theinvention is produced using the three-dimensionally shaped articleproduction method according to the aspect of the invention.

According to this, a three-dimensionally shaped article with excellentdimensional accuracy can be provided.

BRIEF DESCRIPTION OF THE DRAWINGS

The invention will be described with reference to the accompanyingdrawings, wherein like numbers reference like elements.

FIGS. 1A to 1H show cross-sectional views schematically illustratingrespective steps in a preferred embodiment of a three-dimensionallyshaped article production method according to the invention.

FIG. 2 is a perspective view schematically showing a preferredembodiment of a three-dimensionally shaped article production memberaccording to the invention.

FIG. 3 is a cross-sectional view schematically showing a preferredembodiment of a three-dimensionally shaped article production apparatusaccording to the invention.

DESCRIPTION OF EXEMPLARY EMBODIMENTS

Hereinafter, preferred embodiments of the invention will be described indetail with reference to the accompanying drawings.

Three-Dimensionally Shaped Article Production Method andThree-Dimensionally Shaped Article Production Member

First, a three-dimensionally shaped article production method and athree-dimensionally shaped article production member according to theinvention will be described.

FIGS. 1A to 1H are cross-sectional views schematically showingrespective steps in a preferred embodiment of a three-dimensionallyshaped article production method according to the invention. FIG. 2 is aperspective view schematically showing a preferred embodiment of athree-dimensionally shaped article production member according to theinvention.

As shown in FIGS. 1A to 1H, the production method of this embodiment isconfigured as follows. The method includes a layer forming step (FIGS.1A and 1D) in which a layer 1 having a given thickness is formed using acomposition containing particles (layer forming composition) 11, abinding solution application step (FIGS. 1B and 1E) in which a bindingsolution 12 is applied to the layer 1 by an inkjet method, and a curingstep (FIGS. 1C and 1F) in which a cured part (bonded part) 13 is formedin the layer 1 by curing a bonding agent contained in the bindingsolution 12 applied to the layer 1 to bond the particles to one another.These steps are sequentially and repeatedly performed (FIG. 1G), and themethod further includes thereafter an unbonded particle removal step(FIG. 1H) in which among the particles constituting the respectivelayers 1, the particles which are not bonded to one another by thebonding agent are removed.

In the layer forming step, the layer 1 is formed using the layer formingcomposition 11 containing particles in a region which overlaps with athree-dimensionally shaped article production member 8 having pores 811when viewed in plan view (see FIGS. 1A and 1D).

Then, in a series of these steps to be repeatedly performed, the layer 1is sucked toward the stage 41 side through the pores 811. By doing this,undesirable scattering of the particles (powder) in the productionprocess for a three-dimensionally shaped article 10 can be prevented,and the three-dimensionally shaped article 10 with excellent dimensionalaccuracy can be produced with excellent productivity. In addition,scattered particles are prevented from penetrating into an undesirableportion of the production apparatus for the three-dimensionally shapedarticle 10 or adhering thereto, and therefore, the occurrence of aproblem in the apparatus can be effectively prevented, and thus, thestability of production of the three-dimensionally shaped article 10 canbe made excellent. Further, since scattering of the particles can beprevented, the three-dimensionally shaped article 10 can be safelyproduced.

In the case where the composition 11 contains a solvent as described indetail later, the solvent can be efficiently removed from the layer 1 bysuction through the pores 811. In the related art, in the case where acomposition containing particles and a solvent is used as a layerforming composition, it is difficult to sufficiently remove the solventfrom the inside of the layer of the composition, and therefore, themechanical strength or dimensional accuracy of a three-dimensionallyshaped article cannot be made sufficiently excellent. In addition, inorder to sufficiently decrease the content of the solvent in the layer,the heating time is sometimes increased, however, in such a case, theproductivity of a three-dimensionally shaped article is significantlydecreased. Further, in the related art, in the case where a compositioncontaining particles and a solvent is used as the layer formingcomposition, the solvent often remains also in the finally obtainedthree-dimensionally shaped article at a relatively high content, andthis causes a decrease in the durability or reliability of thethree-dimensionally shaped article. On the other hand, according to theinvention, even in the case where a composition containing a solvent isused as the layer forming composition, the occurrence of problems asdescribed above can be reliably prevented. Accordingly, the effect ofthe invention is more remarkably exhibited in the case where the layerforming composition contains particles and a solvent.

Hereinafter, the respective steps will be described.

Layer Forming Step

In the layer forming step, a layer 1 having a given thickness is formedusing a composition containing particles (layer forming composition) 11(FIGS. 1A and 1D).

Since the composition 11 contains particles, the mechanical strength andthe like of the finally obtained three-dimensionally shaped article 10can be made excellent.

The composition (layer forming composition) 11 will be described indetail later.

In this step, by using a flattening unit, the layer 1 is formed suchthat the surface is flattened.

In the first layer forming step, the layer 1 is formed to a giventhickness on the surface of a three-dimensionally shaped articleproduction member 8 placed on a stage 41 (FIG. 1A). At this time, theside surface of the three-dimensionally shaped article production member8 and a side surface support section 45 are in a close contact(abutment) state, so that the composition 11 is prevented from fallingbetween the three-dimensionally shaped article production member 8 andthe side surface support section 45.

In each of the second and following layer forming steps, a new layer 1(second layer) is formed on the surface of the layer 1 (first layer)formed in the previous step (FIG. 1D). At this time, the side surface ofthe layer 1 on the three-dimensionally shaped article production member8 (in the case where a plurality of layers 1 are present on thethree-dimensionally shaped article production member 8, at least thelayer 1 provided on the uppermost side) and the side surface supportsection 45 are in a close contact (abutment) state, so that thecomposition 11 is prevented from falling between the three-dimensionallyshaped article production member 8 and the layer 1 on thethree-dimensionally shaped article production member 8.

As described above, in the three-dimensionally shaped article productionmethod of this embodiment, in a series of these steps to be performedrepeatedly, the layer 1 is sucked toward the stage 41 side through thepores 811. The suction of the layer 1 may be performed in at least somesteps in a series of these steps, however, by performing the suction ofthe layer 1 in the layer forming step, effects as described below areobtained.

That is, the layer forming step is a step involving a particularly largemovement of the layer forming composition 11 containing particles in aseries of these steps to be performed repeatedly, and the particles areliable to be scattered in this step. However, by sucking the layer 1toward the stage 41 side in this step, scattering of the particles(powder) in the entire production process for the three-dimensionallyshaped article 10 can be more effectively prevented, and the effect ofthe invention as described above can be more remarkably exhibited.

Further, for example, in the case where the layer forming composition 11contains a solvent, by sucking the layer 1 toward the stage 41 side inthis step, the solvent can be favorably removed in this step. Therefore,it is not necessary to additionally provide a step of removing thesolvent from the layer 1 prior to the below-mentioned binding solutionapplication step and bonded part forming step, or even if a step ofremoving the solvent from the layer 1 is provided, the time required forthis step can be decreased. As a result, the productivity of thethree-dimensionally shaped article 10 can be made particularly excellentwhile having the effect of using the composition 11 containing thesolvent.

The three-dimensionally shaped article production member 8 may be any aslong as it has the pores 811 through which the layer 1 can be sucked,but is constituted by a porous material in this embodiment.

According to this, the three-dimensionally shaped article productionmember 8 can be easily and reliably obtained as a member having thepores (holes) 811 with an appropriate size. Further, the pores 811 canbe easily and reliably prevented from undesirably unevenly existing inthe three-dimensionally shaped article production member 8.

The average pore diameter (hole diameter) of the pores 811 of thethree-dimensionally shaped article production member 8 is preferably 0.1μm or more and 100 μm or less, more preferably 0.1 μm or more and 20 μmor less.

According to this, the suction of the layer 1 through the pores 811 canbe more favorably performed. Further, the ease of cleaning or washing,durability, and the like of the three-dimensionally shaped articleproduction member 8 can be made particularly excellent. In addition, thethree-dimensionally shaped article production member 8 can be easily andreliably produced by a sintering method or the like.

In this embodiment, the three-dimensionally shaped article productionmember 8 includes a first portion 81 which has the pores 811 and asecond portion 82 which does not have the pores 811 or has the pores 811which are sealed.

According to this, the three-dimensionally shaped article productionmember 8 can be favorably adsorbed onto the stage 41 by suction, and forexample, an undesirable positional displacement or the like of thethree-dimensionally shaped article production member 8 in the productionprocess for the three-dimensionally shaped article 10 can be moreeffectively prevented, and thus, the stability of the production of thethree-dimensionally shaped article 10 can be made particularlyexcellent.

In this embodiment, the second portion 82 is provided in a region whichdoes not overlap with a portion constituting a tangible part (bondedpart 13) of the three-dimensionally shaped article 10 in the layer 1when the layer 1 is viewed in plan view.

According to this, a portion which has a large effect on the dimensionalaccuracy of the three-dimensionally shaped article 10 in the layer 1 canbe favorable sucked, and thus, the dimensional accuracy of the finallyobtained three-dimensionally shaped article 10 can be made higher.Further, in the case where the layer forming composition 11 contains asolvent, the solvent can be efficiently removed from the inside of thelayer 1, and the reliability of the bonded part 13 to be formed in thesubsequent step can be made particularly excellent, and also themechanical strength of the three-dimensionally shaped article 10 can bemade particularly excellent. In addition, the productivity of thethree-dimensionally shaped article 10 can be made more excellent.

As shown in FIG. 2, the second portion 82 is provided near the outerperiphery of the surface on which the layer 1 is formed.

According to this, a region where the tangible part (bonded part 13) ofthe three-dimensionally shaped article 10 can be made sufficientlylarge, and a large three-dimensionally shaped article 10 can befavorably produced. Further, an effect that more three-dimensionallyshaped articles 10 can be simultaneously produced and the like areobtained. In addition, the three-dimensionally shaped articles 10 invarious shapes can be favorably produced without being excessivelylimited by the shape of the three-dimensionally shaped article 10 to beproduced. Further, the three-dimensionally shaped article productionmember 8 can be more favorably adsorbed onto the stage 41, anundesirable positional displacement or the like of thethree-dimensionally shaped article production member 8 in the productionprocess for the three-dimensionally shaped article 10 can be moreeffectively prevented, and thus, the stability of the production of thethree-dimensionally shaped article 10 and the dimensional accuracy,reliability, and the like of the three-dimensionally shaped article 10to be produced can be made particularly excellent.

As described above, the second portion 82 is provided near the outerperiphery, but is preferably provided in a region within 0.2×L (mm),more preferably in a region within 0.1×L (mm) from the outer peripheryof the three-dimensionally shaped article production member 8 when thelength (width) of the surface on which the layer 1 is formed isrepresented by L (mm).

According to this, the effect as described above is more remarkablyexhibited.

In the structure shown in the drawing, the three-dimensionally shapedarticle production member 8 has a plurality of second portions 82, butmay have only one second portion 82. Further, in the structure shown inthe drawing, the second portion 82 is provided in the form of a dot,however, the form of the second portion 82 is not particularly limited,and may be provided in the form of, for example, a frame.

The porosity in the first portion 81 of the three-dimensionally shapedarticle production member 8 is preferably 5% by volume or more and 50%by volume or less, more preferably 10% by volume or more and 30% byvolume or less.

According to this, the suction of the layer 1 through the pores 811 canbe more favorably performed. Further, the ease of cleaning or washing,durability, and the like of the three-dimensionally shaped articleproduction member 8 can be made particularly excellent. In addition, thethree-dimensionally shaped article production member 8 can be easily andreliably produced by a sintering method or the like.

The three-dimensionally shaped article production member 8 may be in anyform, but is in the form of a plate in this embodiment.

According to this, the three-dimensionally shaped article productionmember 8 can be stably placed on the stage 41, and the handleability ofthe three-dimensionally shaped article production member 8 becomesparticularly excellent.

The thickness of the three-dimensionally shaped article productionmember (shaping plate) 8 (the thickness in the stacking direction of thelayer 1) is preferably 0.5 mm or more and 10 mm or less, more preferably2 mm or more and 5 mm or less.

According to this, the shape stability of the three-dimensionally shapedarticle production member 8 is made more excellent and the handleabilityof the three-dimensionally shaped article production member 8 can bemade further more excellent while keeping the weight of thethree-dimensionally shaped article production member 8 low.

The three-dimensionally shaped article production member 8 is preferablyconstituted by a material with a high strength. Examples of theconstituent material of the three-dimensionally shaped articleproduction member 8 include various metal materials such as stainlesssteel and various ceramic materials. Further, by constituting thethree-dimensionally shaped article production member 8 by a sinteredbody of particles constituted by a metal material or a ceramic material,for example, the three-dimensionally shaped article production member 8can be preferably produced as a member including a portion constitutedby a porous body having the pores 811 as described above. When thethree-dimensionally shaped article production member 8 includes aportion constituted by a sintered body of particles constituted by ametal material or a ceramic material, the strength, heat resistance,durability, weight reduction, and the like of the three-dimensionallyshaped article production member 8 can be made particularly excellent.Further, the shape stability and handleability thereof also becomeexcellent, and thus, it is also possible to favorably transfer themember in a state where a stacked body obtained by staking a pluralityof layers 1 is placed thereon. The three-dimensionally shaped articleproduction member 8 may be provided with a gripper capable of pullingout from the side of the member 8 or a mounting member capable ofmounting the gripper. According to this, the transfer of the member canbe further facilitated.

The surface (including the internal surface of the pore 811) of thethree-dimensionally shaped article production member 8 may be subjectedto a surface treatment. By doing this, for example, the adhesion of theconstituent material of the composition 11 or the constituent materialof the binding solution 12 to the three-dimensionally shaped articleproduction member 8 is more effectively prevented, and the durability ofthe three-dimensionally shaped article production member 8 is made moreexcellent, and thus, the stable production of the three-dimensionallyshaped article 10 can be achieved for a longer period of time. Examplesof a material to be used for the surface treatment of the surface of thethree-dimensionally shaped article production member 8 includefluororesins such as polytetrafluoroethylene.

The size (diameter) of the pore 811 is preferably smaller than that ofthe particle constituting the layer 1, however, by using a combinationenabling at least 95% filtration because of a bridge phenomenon, asufficient effect is exhibited.

A gas sucked through the pores 811 is discharged to the outside throughpores 411 provided in the stage 41.

In this manner, by including the pores 411 in the stage 41, a gas can bedischarged smoothly, and the adjustment of the suction power for thelayer 1 can be favorably adjusted. Further, the three-dimensionallyshaped article production member 8 can be favorably adsorbed onto thestage 41 by the suction, and for example, an undesirable positionaldisplacement or the like of the three-dimensionally shaped articleproduction member 8 in the production process for thethree-dimensionally shaped article 10 can be more effectively prevented,and thus, the stability of the production of the three-dimensionallyshaped article 10 can be made particularly excellent.

The viscosity (a value measured using an E-type viscometer (for example,VISCONIC ELD, manufactured by Tokyo Keiki, Inc. or the like)) of thecomposition 11 in this step is preferably 500 mPa·s or more and 60000mPa·s or less, more preferably 1000 mPa·s or more and 20000 mPa·s orless. According to this, the occurrence of an undesirable variation inthe film thickness of the layer 1 to be formed can be more effectivelyprevented.

The thickness of the layer 1 to be formed in this step is notparticularly limited, but, for example, it is preferably 5 μm or moreand 500 μm or less, more preferably 10 μm or more and 100 μm or less.

According to this, while making the productivity of thethree-dimensionally shaped article 10 sufficiently excellent, theoccurrence of undesirable irregularities or the like in thethree-dimensionally shaped article 10 to be produced is more effectivelyprevented, and the dimensional accuracy of the three-dimensionallyshaped article 10 can be made more excellent.

Binding Solution Application Step

Subsequently, a binding solution 12 for bonding the particlesconstituting the layer 1 is applied to the layer 1 (FIGS. 1B and 1E).

In this step, the binding solution 12 is selectively applied only to aportion corresponding to a tangible part (a portion where a tangiblebody is present) of the three-dimensionally shaped article 10 in thelayer 1.

By doing this, the particles constituting the layer 1 are stronglybonded to one another, whereby a bonded part (cured part) 13 having adesired shape can be formed in the end. Further, the mechanical strengthof the finally obtained three-dimensionally shaped article 10 can bemade excellent.

By forming the bonded part 13 using the binding solution 12, the energyamount required for forming the bonded part 13 can be decreased.

In this embodiment, the application of the binding solution 12 to thelayer 1 is performed by an inkjet method.

According to this, even if the application pattern of the bindingsolution 12 has a finer shape, the binding solution 12 can be appliedwith high reproducibility. As a result, the dimensional accuracy of thefinally obtained three-dimensionally shaped article 10 can be madehigher.

The binding solution 12 may be any as long as it contains a bondingagent having a function to bond the particles, however, in thisembodiment, the binding solution 12 contains a curable resin as thebonding agent and particularly preferably contains a photocurable resin(particularly a UV-curable resin) as the bonding agent.

According to this, the mechanical strength of the finally obtainedthree-dimensionally shaped article 10 and the productivity of thethree-dimensionally shaped article 10 can be made more excellent.Further, this is advantageous also from the viewpoint of the storagestability of the binding solution 12 and the production cost of thethree-dimensionally shaped article 10.

The binding solution 12 will be described in detail later.

As described above, the suction of the layer 1 may be performed in atleast some steps in a series of these steps, however, by performing thesuction of the layer 1 in the binding solution application step, effectsas described below are obtained.

That is, in the binding solution application step, it is necessary tomake the binding solution 12 to sufficiently permeate in the thicknessdirection of the layer 1 (spaces among the particles constituting thelayer 1), however, by performing suction in this step, not onlyscattering of the particles constituting the layer 1 is prevented, butalso permeation of the binding solution 12 into the layer 1 is promoted.As a result, the productivity of the three-dimensionally shaped article10 can be made more excellent. It is also possible to more effectivelyprevent a problem (for example, a decrease in the mechanical strength ofthe three-dimensionally shaped article 10, a decrease in the dimensionalaccuracy thereof, etc.) caused by insufficient permeation of the bindingsolution into the layer 1, and thus, the reliability of thethree-dimensionally shaped article 10 to be produced can be made higher.

In particular, the binding solution 12 contains a photocurable resin,and by performing suction when the binding solution 12 is applied,effects as described below are obtained.

That is, as described above, by performing suction in this step, notonly scattering of the particles constituting the layer 1 is prevented,but also permeation of the binding solution 12 into the layer 1 can bepromoted. In addition, when the binding solution 12 contains aphotocurable resin as the bonding agent, by adjusting the timing oflight irradiation, the timing of curing of the photocurable resin in thesubsequent curing step can be easily adjusted. Accordingly, whilepromoting the permeation of the binding solution 12 into the layer 1,excessive wet-spreading of the binding solution in the layer 1 is moreeffectively prevented, and the bonded part 13 having a desired shape canbe easily and reliably formed in the subsequent curing step.

Curing Step (Bonded Part Forming Step)

After the binding solution 12 is applied to the layer 1 in the bindingsolution application step, the bonding agent contained in the bindingsolution 12 applied to the layer 1 is cured, whereby a cured part(bonded part) 13 is formed (FIGS. 1C and 1F).

In this embodiment, the binding solution 12 contains a curable resin(polymerizable compound) as the bonding agent, and by performing atreatment according to the type of the curable resin or the like in thisstep, the cured part (bonded part) 13 is formed. For example, in thecase where the curable resin (polymerizable compound) is a thermosettingpolymerizable compound (thermosetting resin), curing can be performed byheating, and in the case where the curable resin (polymerizablecompound) is a photocurable polymerizable compound (photocurable resin),curing can be performed by light irradiation.

The binding solution application step and the curing step may beperformed simultaneously. That is, before forming the entire pattern ofthe entire one layer 1, the curing reaction may be allowed tosequentially proceed from a portion to which the binding solution 12 isapplied.

The suction conditions may be changed appropriately.

For example, the suction power may be adjusted according to the number(stacking number) of the layers 1 formed on the three-dimensionallyshaped article production member 8. More specifically, for example, inthe case where the number of the layers 1 formed on thethree-dimensionally shaped article production member 8 is large, thesuction power through the pores 811 provided in the three-dimensionallyshaped article production member 8 may be increased as compared with thecase where the number of the layers 1 formed on the three-dimensionallyshaped article production member is small. According to this, thesuction power applied to the layer 1 provided on the uppermost surfaceis effectively prevented from varying depending on the number (stackingnumber) of the layers 1 formed on the three-dimensionally shaped articleproduction member 8. As a result, the suction of the layer 1 can beperformed under stable conditions regardless of the stacking number.Even in the case where a plurality of layers 1 are stacked, the suctionthrough the pores 811 can be stably performed because of the presence ofspaces among the particles contained in the layer 1.

In the case where the suction of the layer 1 is performed in the layerforming step and the binding solution application step, the suctionpower when the binding solution is applied to the layer 1 (in thebinding solution application step) is preferably lower than when thelayer 1 is formed (in the layer forming step).

According to this, scattering of the particles (powder) in the entireproduction process for the three-dimensionally shaped article 10 can bemore effectively prevented, and also undesirable deformation of thelayer 1 is more effectively prevented so that the bonded part 13 can bemore reliably formed to have a desired shape, and thus, the dimensionalaccuracy and the like of the finally obtained three-dimensionally shapedarticle 10 can be made more excellent.

Unbonded Particle Removal Step

Then, a series of these steps as described above is performed repeatedly(FIG. 1G), and thereafter, as a post-treatment step, an unbondedparticle removal step (FIG. 1H) in which among the particlesconstituting the respective layers 1, the particles which are not bondedto one another by the bonding agent (unbonded particles) are removed isperformed. By doing this, the three-dimensionally shaped article 10 istaken out.

Examples of a specific method of this step include a method in which theunbonded particles are removed by brushing with a brush or the like, amethod in which the unbonded particles are removed by suction, a methodin which a gas such as air is blown, a method in which a liquid such aswater is applied (for example, a method in which a stacked body obtainedas described above is soaked in a liquid, a method in which a liquid issprayed, etc.), and a method in which vibration such as ultrasonicvibration is applied. Further, two or more methods selected from thesemethods can be performed in combination. More specifically, a method inwhich a gas such as air is blown to the stacked body, and thereafter,the stacked body is soaked in a liquid such as water, a method in whichultrasonic vibration is applied to the stacked body while soaking thestacked body in a liquid such as water, and the like can be exemplified.Above all, it is preferred to adopt a method in which a liquidcontaining water is applied to the stacked body obtained as describedabove (particularly, a method in which the stacked body is soaked in aliquid containing water).

In this embodiment, the layer 1 is not formed in contact with the stage41, but is formed in contact with the three-dimensionally shaped articleproduction member 8 placed on the stage 41 and stacked, and therefore, astacked body obtained by repeating a series of these steps can befavorably transferred in a state where the stacked body is placed on thethree-dimensionally shaped article production member 8. Due to this, theunbonded particle removal step can be performed in a state where thestacked body is transferred to a suitable place. Further, thethree-dimensionally shaped article production member 8 has the pores(holes) 811, and therefore, in the case where the member is soaked in aliquid such as water, the liquid such as water can come in contact withthe three-dimensionally shaped article 10 also through the pores (holes)811 in the other surface communicating with the contact surface with thelayer 1, and thus, the three-dimensionally shaped article 10 can beseparated from the three-dimensionally shaped article production member8 without being damaged. Accordingly, the workability in the unbondedparticle removal step can be made excellent, and the productivity of thethree-dimensionally shaped article 10 can be made particularlyexcellent.

According to the production method according to the invention asdescribed above, a three-dimensionally shaped article with excellentdimensional accuracy can be produced with excellent productivity andexcellent stability.

Three-Dimensionally Shaped Article Production Apparatus

Next, the three-dimensionally shaped article production apparatusaccording to the invention will be described.

FIG. 3 is a cross-sectional view schematically showing a preferredembodiment of the three-dimensionally shaped article productionapparatus according to the invention.

A three-dimensionally shaped article production apparatus 100 produces athree-dimensionally shaped article 10 by repeatedly forming a layer 1using a composition containing particles (layer forming composition) 11,and stacking the formed layers 1.

The three-dimensionally shaped article production apparatus 100 of thisembodiment includes a control section 2, a composition supply section(layer forming composition supply section) 3 which stores thecomposition containing particles (layer forming composition) 11, athree-dimensionally shaped article production member 8 having pores 811,a layer forming section 4 which forms the layer 1 using the composition11 supplied from the composition supply section 3, a binding solutionejection section (binding solution application unit) 5 which ejects thebinding solution 12 to the layer 1, a UV irradiation unit (curing unit)6 which irradiates a UV light for curing the binding solution 12, and asuction unit 7 which sucks the layer 1 through the pore 811.

The control section 2 includes a computer 21 and a drive control section22.

The computer 21 is a common desk top computer or the like configured toinclude a CPU, a memory, etc. therein. The computer 21 digitizes theshape of the three-dimensionally shaped article 10 as model data, andoutputs cross-sectional data (slice data) obtained by slicing thethree-dimensionally shaped article 10 into a plurality of parallellayers of thin cross sections to the drive control section 22.

The drive control section 22 functions as a control unit forindividually driving the layer forming section 4, the binding solutionejection section 5, the UV irradiation unit 6, the suction unit 7, andthe like. Specifically, for example, the drive control section 22controls the ejection pattern and the ejection amount of the bindingsolution 12 by the binding solution ejection section 5, the supplyamount of the composition 11 from the composition supply section 3, thedescent amount of a stage 41, the conditions of suction (a suctionpower, a portion to be sucked, etc.) by the suction unit 7, and thelike.

The composition supply section 3 is configured to move under the commandof the drive control section 22 and supply the composition 11 storedtherein to a composition temporary placing section 44.

The three-dimensionally shaped article production member 8 is a member,on the surface of which the layer 1 is formed and stacked, and has thepores 811. The member is configured to be able to suck the layer 1through the pores 811.

It is preferred that the three-dimensionally shaped article productionmember 8 satisfy the above-mentioned conditions.

Further, the three-dimensionally shaped article production member 8 isplaced on the stage 41 when the layer 1 is formed, but is preferablyseparable (detachable) from the stage 41.

According to this, when an unnecessary portion (a portion where a bondedpart 13 is not formed) is removed from a stacked body obtained bystacking a plurality of layers 1, the stacked body can be transferred toanother place in a state where the stacked body is placed on thethree-dimensionally shaped article production member 8. According tothis, the removal of the unnecessary portion can be performed withexcellent workability, and thus, the productivity of thethree-dimensionally shaped article 10 can be made particularlyexcellent.

The layer forming section 4 includes the composition temporary placingsection 44 which temporarily holds the composition 11 supplied from thecomposition supply section 3, a squeegee (flattening unit) 42 whichforms a layer 1 while flattening the composition 11 held by thecomposition temporary placing section 44, a guide rail 43 whichregulates the movement of the squeegee 42, the three-dimensionallyshaped article production member 8, the stage 41 which supports thelayer 1 formed on the three-dimensionally shaped article productionmember 8, and a side surface support section (frame body) 45 whichsurrounds the stage 41 and the three-dimensionally shaped articleproduction member 8.

When a new layer 1 is formed on a previously formed layer 1, thepreviously formed layer 1 is moved relatively downward with respect tothe side surface support section (frame body) 45. By doing this, thethickness of the newly formed layer 1 is defined.

In particular, in this embodiment, when a new layer 1 is formed on apreviously formed layer 1, the stage 41 sequentially descends by a givenamount under the command of the drive control section 22. In thismanner, since the stage 41 is configured to be able to move in the Zdirection (vertical direction), the number of members to be moved foradjusting the thickness of the layer 1 when the new layer 1 is formedcan be decreased, and therefore, the structure of thethree-dimensionally shaped article production apparatus 100 can befurther simplified.

The stage 41 has a flat surface (a portion to which the composition 11is applied).

According to this, the layer 1 having a highly uniform thickness can beeasily and reliably formed. Further, in the three-dimensionally shapedarticle 10 to be produced, the occurrence of undesirable deformation orthe like can be effectively prevented.

The stage 41 is provided with pores 411 penetrating through the stage 41in the thickness direction. The pores 411 are connected to the pores 811provided in the three-dimensionally shaped article production member 8,and a gas sucked from the layer 1 is discharged to the outside throughthe pores 411.

The size (width) of the pore 411 is preferably larger than that of thepore 811 provided in the three-dimensionally shaped article productionmember 8.

According to this, the suction from the layer 1 can be favorablyperformed while reducing the load imposed on the suction unit 7.Further, the three-dimensionally shaped article production member 8 canbe more favorably adsorbed onto the stage 41.

The width (in the case where the planar shape of the pore 411 is acircle, the diameter) of the pore 411 is preferably 0.1 mm or more and10 mm or less, more preferably 0.5 mm or more and 3 mm or less.

According to this, the effect as described above is more remarkablyexhibited. Further, in the case where the pores 411 are formed bymachine processing, the ease of the processing can be made particularlyexcellent.

In the structure shown in the drawing, the pore 411 is provided linearlyin the thickness direction of the stage 41 (the normal direction of thelayer 1), but may have, for example, a bent part or a curved part.Further, the pore 411 penetrates through the stage in the thicknessdirection thereof, but may, for example, open to the side surface of thestage 41.

Further, the stage 41 may be constituted by a porous material. Also insuch a case, the stage 41 can be configured to have the pores 411.

Further, the stage 41 preferably has the pores 411 at least in a portionwhich overlaps with the pores 811 provided in the first portion 81 ofthe three-dimensionally shaped article production member 8 when viewedin plan view from the normal direction of the layer 1 and in the secondportion 82 (a portion in which the pores 811 are not provided).

According to this, the suction of the layer 1 can be favorably performedwhile favorably adsorbing the three-dimensionally shaped articleproduction member 8 onto the stage 41.

The pore 411 may have any shape, and examples of the shape thereof whenviewed in plan view from the normal direction of the layer 1 include acircle, an ellipse, a polygon such as a quadrangle, and an L shape.

The stage 41 is preferably constituted by a material with a highstrength. Examples of the constituent material of the stage 41 includevarious metal materials such as stainless steel.

Further, the surface (including the internal surface of the pore 411) ofthe stage 41 may be subjected to a surface treatment. By doing this, forexample, the adhesion of the constituent material of the composition 11or the constituent material of the binding solution 12 to the stage 41is more effectively prevented, and the durability of the stage 41 ismade more excellent, and thus, the stable production of thethree-dimensionally shaped article 10 can be achieved for a longerperiod of time. Examples of a material to be used for the surfacetreatment of the surface of the stage 41 include fluororesins such aspolytetrafluoroethylene.

The squeegee 42 has an elongated shape extending in the Y direction andincludes a blade having the shape of a tapered or rounded edge at alower tip end.

The length of the blade in the Y direction is equal to or longer thanthe width (the length in the Y direction) of the three-dimensionallyshaped article production member 8 (shaping region).

The three-dimensionally shaped article production apparatus 100 mayinclude a vibration mechanism (not shown) for giving small vibration tothe blade so as to smoothly diffuse the composition 11 with the squeegee42.

The side surface support section (frame body) 45 has a function tosupport the side surface of the layer 1 formed on thethree-dimensionally shaped article production member 8. The side surfacesupport section 45 also has a function to define the area of the layer 1when forming the layer 1.

The side surface support section 45 is preferably constituted by amaterial with a high strength. Examples of the constituent material ofthe side surface support section 45 include various metal materials suchas stainless steel.

Further, the surface (a portion which can come in contact with thecomposition 11) of the side surface support section 45 may be subjectedto a surface treatment. By doing this, for example, the adhesion of theconstituent material of the composition 11 or the constituent materialof the binding solution 12 to the side surface support section 45 ismore effectively prevented, and the durability of the side surfacesupport section 45 is made more excellent, and thus, the stableproduction of the three-dimensionally shaped article 10 can be achievedfor a longer period of time. Further, when the previously formed layer 1is moved relatively downward with respect to the side surface supportsection 45, the occurrence of an undesirable disturbance of the layer 1can be effectively prevented. As a result, the dimensional accuracy andreliability of the finally obtained shaped article 10 can be made moreexcellent. Examples of a material to be used for the surface treatmentof the surface of the side surface support section 45 includefluororesins such as polytetrafluoroethylene.

The binding solution application unit (binding solution ejectionsection) 5 applies the binding solution 12 supplied from the bindingsolution storage section (not shown) to the layer 1.

The binding solution ejection section (binding solution applicationunit) 5 is configured such that the application pattern of the bindingsolution 12 or the like is controlled according to the pattern to beformed for each layer 1 under the command of the drive control section22.

In this embodiment, the binding solution application unit 5 is a bindingsolution ejection section which ejects the binding solution 12 by aninkjet method.

According to this, the binding solution 12 can be applied in a finepattern, and even if the three-dimensionally shaped article 10 has afine structure, the three-dimensionally shaped article 10 can beproduced with higher productivity.

As a liquid droplet ejection system (a system of the inkjet method), apiezo system, a system for ejecting the binding solution 12 by a bubblegenerated by heating the binding solution 12, or the like can be used,however, from the viewpoint that the constituent components of thebinding solution 12 are hardly denatured, and the like, a piezo systemis preferred.

The UV irradiation unit (curing unit) 6 irradiates a UV light for curingthe binding solution 12 applied to the layer 1.

The suction unit 7 has a function to suck the layer 1 so as to bring thelayer 1 into close contact with the three-dimensionally shaped articleproduction member 8 or so as to bring the layer 1 into close contactwith a layer 1 provided closer to the three-dimensionally shaped articleproduction member 8 than the layer 1.

As the suction unit 7, for example, any of various pumps can be used.

According to the three-dimensionally shaped article production apparatusaccording to the invention as described above, a three-dimensionallyshaped article with excellent dimensional accuracy can be produced withexcellent productivity and excellent stability.

Composition (Layer Forming Composition)

Next, the composition (layer forming composition) to be used forproducing the three-dimensionally shaped article according to theinvention will be described in detail.

The composition (layer forming composition) 11 contains a powder forthree-dimensional shaping containing at least a plurality of particles.

Powder (Particles) for Three-Dimensional Shaping

Examples of a constituent material of the particles constituting thepowder for three-dimensional shaping include an inorganic material, anorganic material, and a composite of these materials.

Examples of the inorganic material constituting the particles includevarious metals and metal compounds. Examples of the metal compoundsinclude various metal oxides such as silica, alumina, titanium oxide,zinc oxide, zirconium oxide, tin oxide, magnesium oxide, and potassiumtitanate; various metal hydroxides such as magnesium hydroxide, aluminumhydroxide, and calcium hydroxide; various metal nitrides such as siliconnitride, titanium nitride, and aluminum nitride; various metal carbidessuch as silicon carbide and titanium carbide; various metal sulfidessuch as zinc sulfide; various metal carbonates such as calcium carbonateand magnesium carbonate; various metal sulfates such as calcium sulfateand magnesium sulfate; various metal silicates such as calcium silicateand magnesium silicate; various metal phosphates such as calciumphosphate; various metal borates such as aluminum borate and magnesiumborate; and composites of these materials.

Examples of the organic material constituting the particles includesynthetic resins and natural polymers, and more specific examplesthereof include a polyethylene resin; polypropylene; polyethylene oxide;polypropylene oxide; polyethylenimine; polystyrene; polyurethane;polyurea; polyester; a silicone resin; an acrylic silicone resin; apolymer containing a (meth)acrylate ester as a constituent monomer suchas poly(methyl methacrylate); a crosspolymer (an ethylene acrylic acidcopolymer resin or the like) containing a (meth)acrylate ester as aconstituent monomer such as a methyl methacrylate crosspolymer;polyamide resins such as nylon 12, nylon 6, and copolymer nylon;polyimide; carboxymethyl cellulose; gelatin; starch; chitin; andchitosan.

The particles may be subjected to a surface treatment such as ahydrophobization treatment.

The hydrophobization treatment performed for the particles may be any aslong as it is a treatment for enhancing the hydrophobicity of theparticles (base particles), but is preferably a treatment in which ahydrocarbon group is introduced.

According to this, the hydrophobicity of the particles can be madehigher. Further, the uniformity of the degree of the hydrophobizationtreatment among individual particles and individual portions of thesurface of the particle (in the case where the particle has a poreopening to the outside, including the internal surface of the pore) canbe easily and reliably made higher.

A compound to be used in the hydrophobization treatment is preferably asilane compound containing a silyl group.

The average particle diameter of the particles is not particularlylimited, but is preferably 1 μm or more and 25 μm or less, morepreferably 1 μm or more and 15 μm or less.

According to this, the mechanical strength of the three-dimensionallyshaped article 10 can be made more excellent, and also the occurrence ofundesirable irregularities or the like in the three-dimensionally shapedarticle 10 to be produced is more effectively prevented, and thedimensional accuracy of the three-dimensionally shaped article 10 can bemade more excellent. Further, the fluidity of the layer formingcomposition 11 can be made more excellent, and thus, the productivity ofthe three-dimensionally shaped article 10 can be made more excellent. Inaddition, even in the case where the number (stacking number) of thelayers 1 formed on the three-dimensionally shaped article productionmember 8 is relatively large, the suction through the pores 811 can bemore favorably performed.

The “average particle diameter” as used herein refers to an averageparticle diameter on a volume basis and can be determined by, forexample, adding a sample to methanol, followed by dispersion for 3minutes using an ultrasonic disperser, and then, measuring the resultingdispersion liquid using a particle size distribution analyzer employinga Coulter counter method (for example, model TA-II, manufactured byCoulter Electronics, Inc.) with an aperture of 50 μm.

The Dmax of the particles is preferably 3 μm or more and 40 μm or less,more preferably 5 μm or more and 30 μm or less.

According to this, the mechanical strength of the three-dimensionallyshaped article 10 can be made more excellent, and also the occurrence ofundesirable irregularities or the like in the three-dimensionally shapedarticle 10 to be produced is more effectively prevented, and thedimensional accuracy of the three-dimensionally shaped article 10 can bemade more excellent. Further, the fluidity of the layer formingcomposition 11 can be made more excellent, and thus, the productivity ofthe three-dimensionally shaped article 10 can be made more excellent.

The particles may have any shape, but preferably have a spherical shape.According to this, the fluidity of the layer forming composition 11 canbe made more excellent, and thus, the productivity of thethree-dimensionally shaped article 10 can be made more excellent, andalso the occurrence of undesirable irregularities or the like in thethree-dimensionally shaped article 10 to be produced is more effectivelyprevented, and the dimensional accuracy of the three-dimensionallyshaped article 10 can be made more excellent.

The layer forming composition 11 may contain a plurality of types ofparticles.

The content of the particles in the layer forming composition 11 ispreferably 8% by mass or more and 100% by mass or less, more preferably10% by mass or more and 100% by mass or less.

According to this, while making the fluidity of the layer formingcomposition 11 sufficiently excellent, the mechanical strength of thefinally obtained three-dimensionally shaped article 10 can be made moreexcellent.

Solvent

The layer forming composition 11 may contain a solvent in addition tothe particles.

According to this, for example, the layer forming composition 11 can beformed into a paste, and the fluidity of the layer forming composition11 can be increased, and the workability when forming the layer 1 can beenhanced, and also the layer 1 with high surface flatness can be easilyand reliably formed. Further, undesirable scattering or the like of thepowder (particles) when forming the layer 1 or the like can be moreeffectively prevented. In the related art, in the case where acomposition containing particles and a solvent is used as the layerforming composition, it is difficult to sufficiently remove the solventfrom the inside of the layer of the composition, and therefore, themechanical strength or dimensional accuracy of the three-dimensionallyshaped article cannot be made sufficiently excellent. Further, theheating time is sometimes increased in order to sufficiently decreasethe content of the solvent in the layer, however, in such a case, theproductivity of a three-dimensionally shaped article is significantlydecreased. Further, in the related art, in the case where a compositioncontaining particles and a solvent is used as the layer formingcomposition, the solvent often remains also in the finally obtainedthree-dimensionally shaped article at a relatively high content, andthis causes a decrease in the durability or reliability of thethree-dimensionally shaped article. On the other hand, according to theinvention, even in the case where a composition containing a solvent isused as the layer forming composition, the occurrence of problems asdescribed above can be reliably prevented. Accordingly, the effect ofthe invention is more remarkably exhibited in the case where the layerforming composition contains particles and a solvent.

Further, particularly in the case where the layer forming composition 11contains an aqueous solvent among various solvents, effects as describedbelow are obtained.

That is, the aqueous solvent has high affinity for water, and thereforecan favorably dissolve a water-soluble resin described later. Therefore,the fluidity of the layer forming composition 11 can be made favorable,and an undesirable variation in the thickness of the layer 1 to beformed using the layer forming composition 11 can be more effectivelyprevented. Further, when the layer 1 in a state where the aqueoussolvent has been removed is formed, a water-soluble resin can be adheredto the particle with higher uniformity throughout the entire layer 1,and thus, the occurrence of undesirable unevenness of the compositioncan be more effectively prevented. Due to this, the occurrence of anundesirable variation in the mechanical strength among individualportions of the finally obtained three-dimensionally shaped article 10can be more effectively prevented, and thus, the reliability of thethree-dimensionally shaped article 10 can be made higher.

The “aqueous solvent” as used herein refers to water or a liquid havinghigh affinity for water, however, specifically refers to a solventhaving a solubility in 100 g of water at 25° C. of 50 g or more.

Examples of the aqueous solvent constituting the layer formingcomposition 11 include water; alcoholic solvents such as methanol,ethanol, and isopropanol; ketone-based solvents such as methyl ethylketone and acetone; glycol ether-based solvents such as ethylene glycolmonoethyl ether and ethylene glycol monobutyl ether; glycol etheracetate-based solvents such as propylene glycol 1-monomethyl ether2-acetate and propylene glycol 1-monoethyl ether 2-acetate; polyethyleneglycol, and polypropylene glycol, and one solvent or a combination oftwo or more solvents selected from these can be used.

The content of the solvent in the layer forming composition 11 ispreferably 1% by mass or more and 92% by mass or less, more preferably2% by mass or more and 89% by mass or less.

According to this, the effect of including the solvent as describedabove is more remarkably exhibited, and also the solvent can be easilyremoved in a short time in the production process for thethree-dimensionally shaped article 10, and thus, the productivity of thethree-dimensionally shaped article 10 can be made more excellent.Further, spaces can be incorporated in the layer 1 in a state where thesolvent has been removed at an appropriate ratio so that thepermeability of the binding solution 12 can be made more excellent, andthus, the mechanical strength, dimensional accuracy, and the like of thefinally obtained three-dimensionally shaped article 10 can be made moreexcellent.

Binder

The layer forming composition 11 may contain a binder.

According to this, a plurality of particles can be favorably bonded(temporarily fixed) to one another in the layer 1 formed using the layerforming composition 11, and thus, undesirable scattering or the like ofthe particles can be effectively prevented. As a result, the safety forworkers and the dimensional accuracy of the three-dimensionally shapedarticle 10 to be produced can be further improved.

In the case where the layer forming composition 11 contains a solventand a binder, the binder is preferably dissolved in the solvent in thelayer forming composition 11.

According to this, the fluidity of the layer forming composition 11 canbe made more favorable, and an undesirable variation in the thickness ofthe layer 1 to be formed using the layer forming composition 11 can bemore effectively prevented. Further, when the layer 1 in a state wherethe solvent has been removed is formed, the binder can be adhered to theparticles with higher uniformity throughout the entire layer 1, andthus, the occurrence of undesirable unevenness of the composition can bemore effectively prevented. Due to this, the occurrence of anundesirable variation in the mechanical strength among individualportions of the finally obtained three-dimensionally shaped article 10can be more effectively prevented, and thus, the reliability of thethree-dimensionally shaped article 10 can be made higher.

The binder may be any as long as it has a function to temporarily fix aplurality of particles in the layer 1 formed using the layer formingcomposition 11, however, a water-soluble resin can be preferably used.

By including a water-soluble resin, in the case where the layer formingcomposition 11 contains an aqueous solvent (particularly water) as thesolvent, the binder (water-soluble resin) can be included in the layerforming composition 11 in a dissolved state, and the fluidity andhandleability (ease of handling) of the layer forming composition 11 canbe made more excellent. As a result, the productivity of thethree-dimensionally shaped article 10 can be made more excellent.

Further, a portion of the layer 1 to which the binding solution 12 isnot applied in the production process for the three-dimensionally shapedarticle 10 can be easily and efficiently removed by applying an aqueoussolvent (particularly water) thereto. As a result, the productivity ofthe three-dimensionally shaped article 10 can be made more excellent.Further, the portion of the layer 1 which should be removed can beeasily and reliably prevented from adhering to or remaining in thefinally obtained three-dimensionally shaped article 10, and thus, thedimensional accuracy of the three-dimensionally shaped article 10 can bemade more excellent.

Hereinafter, the water-soluble resin as the binder will be mainlydescribed.

The water-soluble resin may be any as long as it can be at leastpartially dissolved in an aqueous solvent, but is preferably, forexample, a resin having a solubility in water (the mass of the resinthat can be dissolved in 100 g of water) at 25° C. of 5 g/100 g of wateror more, more preferably a resin having a solubility in water at 25° C.of 10 g/100 g of water or more.

Examples of the water-soluble resin include synthetic polymers such aspolyvinyl alcohol (PVA), polyvinylpyrrolidone (PVP), polycaprolactonediol, sodium polyacrylate, ammonium polyacrylate, polyacrylamide,modified polyamide, polyethylenimine, polyethylene oxide, and a randomcopolymer of ethylene oxide and propylene oxide; natural polymers suchas corn starch, mannan, pectin, agar, alginic acid, dextran, glue, andgelatin; and semisynthetic polymers such as carboxymethyl cellulose,hydroxyethyl cellulose, oxidized starch, and modified starch, and onematerial or a combination of two or more materials selected from thesecan be used.

Binding Solution

Next, the binding solution to be used for the production of thethree-dimensionally shaped article 10 according to the invention will bedescribed in detail.

The binding solution 12 contains at least a bonding agent.

Bonding Agent

The binding solution 12 contains at least a curable resin as the bondingagent.

Examples of the curable resin include a thermosetting resin; variousphotocurable resins such as a visible light curable resin which is curedby a light in the visible light range (a photocurable resin in a narrowsense), a UV curable resin, and an IR curable resin; and an X-raycurable resin, and one curable resin or a combination of two or morecurable resins selected from these can be used. Above all, particularly,a UV curable resin (polymerizable compound) is preferred from theviewpoint of the mechanical strength of the three-dimensionally shapedarticle 10 to be obtained, the productivity of the three-dimensionallyshaped article 10, the storage stability of the binding solution 12, andthe like.

As the UV curable resin (polymerizable compound), a compound whoseaddition polymerization or ring-opening polymerization is initiated by aradical species, a cationic species, or the like generated from aphotopolymerization initiator by UV irradiation, thereby forming apolymer is preferably used. Examples of the polymerization form of theaddition polymerization include radical, cationic, anionic, metathesis,and coordination polymerization. Further, examples of the polymerizationform of the ring-opening polymerization include cationic, anionic,radical, metathesis, and coordination polymerization.

Examples of an addition polymerizable compound include compounds havingat least one ethylenically unsaturated double bond. As the additionpolymerizable compound, a compound having at least one, preferably twoor more terminal ethylenically unsaturated bonds can be preferably used.

An ethylenically unsaturated polymerizable compound has a chemical formof a monofunctional polymerizable compound, a polyfunctionalpolymerizable compound, or a mixture thereof. Examples of themonofunctional polymerizable compound include unsaturated carboxylicacids (for example, acrylic acid, methacrylic acid, itaconic acid,crotonic acid, isocrotonic acid, maleic acid, etc.) and esters thereof,and amides thereof. As the polyfunctional polymerizable compound, anester of an unsaturated carboxylic acid with an aliphatic polyhydricalcohol compound or an amide of an unsaturated carboxylic acid with analiphatic polyvalent amine compound is used.

Further, an addition reaction product of an ester or an amide of anunsaturated carboxylic acid having a hydroxyl group or a nucleophilicsubstituent such as an amino group or a mercapto group with anisocyanate or an epoxy, a dehydration condensation reaction product witha carboxylic acid, or the like can also be used. Further, an additionreaction product of an ester or an amide of an unsaturated carboxylicacid having an electrophilic substituent such as an isocyanate group oran epoxy group with an alcohol, an amine, or a thiol, further, asubstitution reaction product of an ester or an amide of an unsaturatedcarboxylic acid having a leaving substituent such as a halogen group ora tosyloxy group with an alcohol, an amine, or a thiol can also be used.

As a specific example of the radical polymerizable compound which is theester of an unsaturated carboxylic acid with an aliphatic polyhydricalcohol compound, for example, a (meth)acrylate ester is representative,and either a monofunctional (meth)acrylate or a polyfunctional(meth)acrylate can be used.

The content of the bonding agent in the binding solution 12 ispreferably 80% by mass or more, more preferably 85% by mass or more.According to this, the mechanical strength of the finally obtainedthree-dimensionally shaped article 10 can be made particularlyexcellent.

Another Component

The binding solution 12 may contain a component other than theabove-mentioned components. Examples of such a component include variouscoloring agents such as a pigment and a dye, a dispersant, a surfactant,a polymerization initiator, a polymerization accelerator, a solvent, apermeation accelerator, a wetting agent (humectant), a fixing agent, anantifungal agent, a preservative, an antioxidant, a UV absorber, achelating agent, a pH adjusting agent, a thickening agent, a filler, ananti-aggregation agent, and a defoaming agent.

In the case where the binding solution 12 contains a pigment, theaverage particle diameter of the pigment is preferably 300 nm or less,more preferably 50 nm or more and 250 nm or less. According to this, theejection stability of the binding solution 12 and the dispersionstability of the pigment in the binding solution 12 can be made moreexcellent, and also an image with higher image quality can be formed.

The binding solution 12 may contain a solvent. According to this, theviscosity of the binding solution 12 can be favorably adjusted, and evenif the binding solution 12 contains a component with a high viscosity,the ejection stability of the binding solution 12 by an inkjet methodcan be made more excellent.

Examples of the solvent include (poly)alkylene glycol monoalkyl etherssuch as ethylene glycol monomethyl ether, ethylene glycol monoethylether, propylene glycol monomethyl ether, and propylene glycol monoethylether; acetate esters such as ethyl acetate, n-propyl acetate,iso-propyl acetate, n-butyl acetate, and iso-butyl acetate; aromatichydrocarbons such as benzene, toluene, and xylene; ketones such asmethyl ethyl ketone, acetone, methyl isobutyl ketone, ethyl-n-butylketone, diisopropyl ketone, and acetyl acetone; and alcohols such asethanol, propanol, and butanol, and one solvent or a combination of twoor more solvents selected from these can be used.

The viscosity of the binding solution 12 is preferably 1 mPa·s or moreand 30 mPa·s or less, more preferably 3 mPa·s or more and 25 mPa·s orless. According to this, the ejection stability of the binding solution12 by an inkjet method can be made more excellent. Incidentally, the“viscosity” as used herein refers to a value measured at 25° C. using anE-type viscometer (for example, VISCONIC ELD, manufactured by TokyoKeiki, Inc. or the like) unless otherwise specified.

Three-Dimensionally Shaped Article

The three-dimensionally shaped article according to the invention can beproduced using the production method and the production apparatus asdescribed above.

According to this, a three-dimensionally shaped article with excellentdimensional accuracy can be provided.

The use of the three-dimensionally shaped article according to theinvention is not particularly limited, however, examples of the useinclude ornaments and exhibits such as dolls and figures; and medicaldevices such as implants.

Further, the three-dimensionally shaped article according to theinvention may be applied to any of prototypes, mass-produced products,and custom-made products.

Hereinabove, preferred embodiments of the invention have been described,however, the invention is not limited thereto.

For example, in the three-dimensionally shaped article productionapparatus according to the invention, the configuration of each sectioncan be replaced with an arbitrary configuration exhibiting a similarfunction, and also an arbitrary configuration can be added.

For example, in the above-mentioned embodiments, a configuration inwhich the stage is moved down has been representatively described,however, in the production method according to the invention, forexample, the side surface support section may be configured to move up.

Further, a roller or the like may be used as the flattening unit inplace of the squeegee as described above.

Further, the three-dimensionally shaped article production apparatusaccording to the invention may include a recovery mechanism (not shown)for recovering the composition which is not used for forming the layerin the composition supplied from the composition supply section.According to this, while preventing the accumulation of the excesscomposition in the layer forming section, a sufficient amount of thecomposition can be supplied, and therefore, while more effectivelypreventing the occurrence of defects in the layer, thethree-dimensionally shaped article can be produced more stably. Further,the recovered composition can be used for producing thethree-dimensionally shaped article again, and therefore, this cancontribute to the reduction in the production cost of thethree-dimensionally shaped article, so that this configuration ispreferred also from the viewpoint of resource saving.

Further, the three-dimensionally shaped article production apparatusaccording to the invention may include a recovery mechanism forrecovering the composition removed in the unbonded particle removalstep.

Further, in the case where a material containing a solvent (for example,the layer forming composition, the binding solution, or the like) isused for producing the three-dimensionally shaped article, thethree-dimensionally shaped article production apparatus according to theinvention may include a solvent recovery unit for recovering the solventremoved from the layer. The solvent recovery unit can be disposed, forexample, in a flow channel connected to the suction unit. As the solventrecovery unit, for example, a Dewar condenser, an Allihn condenser, aGraham condenser, a Dimroth condenser, a Liebig condenser, a Friedrichscondenser, a Hopkins condenser, a West condenser, a cold finger, or thelike can be adopted.

Further, the three-dimensionally shaped article production apparatus mayinclude, for example, a heating unit for heating the layer. According tothis, for example, in the case where a material containing a solvent(for example, the layer forming composition, the binding solution, orthe like) is used for producing the three-dimensionally shaped article,the fluidity of the solvent can be made more excellent so that theefficiency of removing the solvent can be made more excellent, and thus,the productivity of the three-dimensionally shaped article can be mademore excellent. Further, the solvent can be more effectively preventedfrom undesirably remaining in the three-dimensionally shaped article tobe produced, and thus, the reliability and the like of thethree-dimensionally shaped article can be made more excellent.

Further, in the above-mentioned embodiments, a case where thethree-dimensionally shaped article production member to be placed on thestage is constituted by a porous body, and the layer is sucked throughthe pores (continuous pores) of the porous body has been mainlydescribed, however, the three-dimensionally shaped article productionmember may not be constituted by a porous body, and for example, mayhave pores provided linearly in the thickness direction. Such pores maybe provided by, for example, machine processing.

Further, in the above-mentioned embodiments, a case where poresfunctioning as flow channels for a gas are provided in the stage hasbeen representatively described, however, the stage may not have pores.

For example, a three-dimensionally shaped article production memberhaving a larger area than the stage is used, and suction may beperformed from a portion which is not in contact with the stage of thesurface facing the stage of the three-dimensionally shaped articleproduction member.

Further, in the above-mentioned embodiments, a case where the bindingsolution application step is performed by an inkjet method has beenmainly described, however, the binding solution application step may beperformed using another method (for example, another printing method).

Further, in the above-mentioned embodiments, a case where the flatteningunit moves on the stage has been described, however, the flattening maybe performed by moving the stage so as to change the positionalrelationship between the stage and the squeegee.

Further, the three-dimensionally shaped article production apparatusaccording to the invention may be any as long as it is configured suchthat the three-dimensionally shaped article production member havingpores is used and the layer can be sucked through the pores, and may nothave a configuration as described above. For example, thethree-dimensionally shaped article production apparatus according to theinvention may not include the binding solution application unit or thecuring unit.

Further, in the above-mentioned embodiments, a case where the bondedpart is formed in all the layers has been described, however, a layer inwhich the bonded part is not formed may be formed. For example, thebonded part is not formed in a layer formed immediately above the stage,and the layer may be made to function as a sacrifice layer.

Further, in the production method according to the invention, apre-treatment step, an intermediate treatment step, or a post-treatmentstep may be performed as needed.

Examples of the pre-treatment step include a stage cleaning step.

Examples of the post-treatment step include a washing step, a shapeadjustment step in which deburring or the like is performed, a coloringstep, a coating layer forming step, and a bonding agent curingcompletion step in which a UV irradiation treatment for reliably curingthe uncured bonding agent is performed.

Further, in the above-mentioned embodiments, a case where the bindingsolution contains a curable resin (polymerizable compound) has beenmainly described, however, the binding solution may contain athermoplastic resin in place of the curable resin (polymerizablecompound). Even in such a case, the bonded part can be formed byconverting the thermoplastic resin from a dissolved state to asolidified state, or by removing a solvent contained in the bindingsolution (a solvent for dissolving the thermoplastic resin) to convertthe thermoplastic resin to a solidified state, or the like.

Further, in the above description, a case where the formation of thebonded part is performed using the binding solution has been mainlydescribed, however, in the invention, the formation of the bonded partmay be performed by any method, and may be performed by, for example,fusing (sintering, joining) the particles with irradiation with anenergy light.

In such a method, in the related art, the temperature of a regionirradiated with the energy light and a region therearound is increased,and therefore, a problem arises such that the dimensional accuracy isliable to be decreased due to the thermal expansion. However, accordingto the invention, gas flow can be generated accompanying the suction ofthe layer, and therefore, the temperature of a region irradiated withthe energy light and a region therearound can be prevented fromincreasing. Further, even in the case where the temperature is increasedto a relatively high level by the irradiation with the energy light, thematerial can be rapidly cooled. As a result, the dimensional accuracy ofthe finally obtained three-dimensionally shaped article can be reliablymade excellent. Further, the time required for cooling can be decreased,and therefore, the productivity of the three-dimensionally shapedarticle can be made particularly excellent. The method in which theparticles are fused (sintered, joined) by irradiation with an energylight has a problem that the temperature of a region irradiated with theenergy light is rapidly increased when the energy light for fusing(sintering, joining) the particles is irradiated and the particlesconstituting the layer are liable to be scattered. However, according tothe invention, the problem as described above can be reliably prevented.

In addition, even in the case where an energy light with high energy isirradiated, the occurrence of the problem as described above can bereliably prevented, and therefore, an energy light with high energy canbe favorably used, and the efficiency of forming the bonded part can beincreased. As a result, the productivity of the three-dimensionallyshaped article can be made particularly excellent.

The entire disclosure of Japanese patent No. 2015-020009, filed Feb. 4,2015 is expressly incorporated by reference herein.

What is claimed is:
 1. A three-dimensionally shaped article productionmember, which is a member used in a three-dimensionally shaped articleproduction apparatus for producing a three-dimensionally shaped articleby stacking a layer formed using a composition containing particles,wherein the member is placed on a stage and comes in contact with thelayer, and the member has a portion provided with pores in a contactsurface with the layer.
 2. The three-dimensionally shaped articleproduction member according to claim 1, wherein the three-dimensionallyshaped article production member is in the form of a plate.
 3. Thethree-dimensionally shaped article production member according to claim1, wherein the three-dimensionally shaped article production memberincludes a first portion which has the pores and a second portion whichdoes not have the pores or has the pores which are sealed.
 4. Thethree-dimensionally shaped article production member according to claim3, wherein the second portion is provided in a region which does notoverlap with a portion constituting a tangible part of thethree-dimensionally shaped article in the layer when the layer is viewedin plan view.
 5. The three-dimensionally shaped article productionmember according to claim 1, wherein the three-dimensionally shapedarticle production member has a portion constituted by a sintered bodyof particles constituted by a metal material or a ceramic material. 6.The three-dimensionally shaped article production member according toclaim 1, wherein the average pore diameter of the pores is 0.1 μm ormore and 100 μm or less.
 7. The three-dimensionally shaped articleproduction member according to claim 1, wherein the composition containsa solvent in addition to the particles.
 8. A three-dimensionally shapedarticle production apparatus, comprising the three-dimensionally shapedarticle production member according to claim
 1. 9. A three-dimensionallyshaped article production apparatus, which is an apparatus for producinga three-dimensionally shaped article by stacking a layer formed using acomposition containing particles, comprising: a three-dimensionallyshaped article production member having pores; a stage, on which thethree-dimensionally shaped article production member is placed; and asuction unit for sucking the layer through the pores.
 10. Athree-dimensionally shaped article production method, which is a methodfor producing a three-dimensionally shaped article by stacking a layer,comprising: a layer forming step of forming the layer using a layerforming composition containing particles in a region which overlaps witha three-dimensionally shaped article production member having pores whenviewed in plan view; and a bonded part forming step of forming a bondedpart by bonding the particles to one another, wherein a series of thesesteps is performed repeatedly, and when performing a series of thesesteps, the layer is sucked through the pores.
 11. Thethree-dimensionally shaped article production method according to claim10, wherein the bonded part is formed by applying a binding solution tothe layer formed using the layer forming composition.
 12. Athree-dimensionally shaped article, which is produced using theapparatus according to claim
 8. 13. A three-dimensionally shapedarticle, which is produced using the apparatus according to claim
 9. 14.A three-dimensionally shaped article, which is produced using theproduction method according to claim
 10. 15. A three-dimensionallyshaped article, which is produced using the production method accordingto claim 11.